| Date | 9 August 2016 — 14:07 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | James Keothavong |  GBR |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| – | Mónica Puig |  PUR | 2 | 2 | 6 | 6 | |
| 3 | Garbiñe Muguruza |  ESP | 0 | 0 | 1 | 1 |
| Mónica Puig | Garbiñe Muguruza | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 1 |
| Set 2 | 6 | 1 |
