| Date | 9 August 2016 — 10:48 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Alison Hughes |  GBR |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 7 | Madison Keys |  USA | 2 | 6 | 3 | 6 | |
| 9 | Carla Suárez |  ESP | 1 | 3 | 6 | 3 |
| Madison Keys | Carla Suárez | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 6 | 3 |
| Set #2 | 3 | 6 |
| Set #3 | 6 | 3 |
