| Date | 8 August 2016 — 11:04 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Gianluca Moscarella |  ITA |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|
| 7 | Madison Keys |  USA | 2 | 7 | 6 (4) | 7 (7) | |
| – | Kristina Mladenovic |  FRA | 1 | 5 | 7 (7) | 6 (5) |
| Madison Keys | Kristina Mladenovic | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 7 | 5 |
| Set 2 | 6 (4) | 7 (7) |
| Set 3 | 7 (7) | 6 (5) |
