| | Top level | Event type
Singles, Women – Match #16
| Date | 8 August 2016 — 12:43 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Félix Torralba |  ESP |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 2 | Angelique Kerber |  GER | 2 | 6 | 6 | |
| – | Eugenie Bouchard |  CAN | 0 | 4 | 2 |
| Angelique Kerber | Eugenie Bouchard | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 4 |
| Set 2 | 6 | 2 |