| Date | 7 August 2016 — 12:38 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Marijana Veljović |  SRB |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 1 | Serena Williams |  USA | 2 | 2 | 6 | 6 | |
| – | Daria Gavrilova |  AUS | 0 | 0 | 4 | 2 |
| Serena Williams | Daria Gavrilova | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 4 |
| Set 2 | 6 | 2 |
