| Date | 6 August 2016 — 12:28 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Mariana Alves |  POR |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| 9 | Carla Suárez |  ESP | 2 | 2 | 2 | 6 | 6 | |
| – | Ana Ivanović |  SRB | 1 | 1 | 6 | 1 | 2 |
| Carla Suárez | Ana Ivanović | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 2 | 6 |
| Set 2 | 6 | 1 |
| Set 3 | 6 | 2 |
