| Date | 6 August 2016 — 11:06 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Ali Nili |  USA |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 16 | Barbora Strýcová |  CZE | 2 | 7 (8) | 6 | |
| – | Yanina Wickmayer |  BEL | 0 | 6 (6) | 1 |
| Barbora Strýcová | Yanina Wickmayer | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 7 (8) | 6 (6) |
| Set 2 | 6 | 1 |
