| Date | 12 August 2016 — 18:03 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Nico Helwerth |  GER |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 4 | Sania Mirza / Rohan Bopanna |  IND | 2 | 2 | 6 | 6 | |
| – | Heather Watson / Andy Murray |  GBR | 0 | 0 | 4 | 4 |
Sania Mirza / Rohan Bopanna| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Sania Mirza | ||||
| – | Rohan Bopanna | ||||
| Team Totals | |||||
Heather Watson / Andy Murray| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Heather Watson | ||||
| – | Andy Murray | ||||
| Team Totals | |||||
