| Date | 11 August 2016 — 16:29 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Marija Čičak |  CRO |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| – | Teliana Pereira / Marcelo Melo |  BRA | 2 | 7 (7) | 7 (7) | |
| 1 | Caroline Garcia / Nicolas Mahut |  FRA | 0 | 6 (4) | 6 (1) |
Teliana Pereira / Marcelo Melo| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Teliana Pereira | ||||
| – | Marcelo Melo | ||||
| Team Totals | |||||
Caroline Garcia / Nicolas Mahut| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Caroline Garcia | ||||
| – | Nicolas Mahut | ||||
| Team Totals | |||||
