| Date | 11 August 2016 — 18:59 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court TBA) | |
| Chair Umpire | Thomas Sweeney |  AUS |
| Seed | Competitor | NOC | ||
|---|---|---|---|---|
| – | Lucie Hradecká / Radek Štěpánek |  CZE | walkover | |
| 3 | Garbiñe Muguruza / Rafael Nadal |  ESP |
Lucie Hradecká / Radek Štěpánek| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Lucie Hradecká | ||||
| – | Radek Štěpánek | ||||
| Team Totals | walkover | ||||
Garbiñe Muguruza / Rafael Nadal| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Garbiñe Muguruza (DNS) | ||||
| – | Rafael Nadal (DNS) | ||||
| Team Totals | |||||
