| Date | 23 September 2000 — 19:00 | |
|---|---|---|
| Location | New South Wales Tennis Centre, Olympic Park, Sydney, New South Wales (Show Court #1) | |
| Chair Umpire | Pascal Maria |  FRA |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 2 | Guga Kuerten |  BRA | 2 | 2 | 7 | 6 | |
| – | Ivan Ljubičić |  CRO | 0 | 0 | 6 | 3 |
| Guga Kuerten | Ivan Ljubičić | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 7 | 6 |
| Set 2 | 6 | 3 |
| Tie-break 1 | 7 | 2 |
