| Date | 24 August 2014 |
|---|---|
| Location | Tennis Academy of China, Nanjing Sport Institute, Xuanwu, Nanjing |
| Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|
| Marcelo Silva / Orlando Luz |  BRA | 2 | 7 | 3 | |
| Karen Khachanov / Andrey Rublyov |  RUS | 1 | 5 | 6 |
Marcelo Silva / Orlando Luz| Pos | Competitor | Match Tie-break | |||
|---|---|---|---|---|---|
| Marcelo Silva | – | ||||
| Orlando Luz | – | ||||
| Team Totals | 10 | ||||
Karen Khachanov / Andrey Rublyov| Pos | Competitor | Match Tie-break | |||
|---|---|---|---|---|---|
| Karen Khachanov | – | ||||
| Andrey Rublyov | – | ||||
| Team Totals | 3 | ||||
