| Date | 11 August 2016 — 11:04 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Carlos Bernardes |  BRA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 7 | Madison Keys |  USA | 2 | 6 | 6 | |
| – | Darya Kasatkina |  RUS | 0 | 3 | 1 |
| Madison Keys | Darya Kasatkina | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 6 | 3 |
| Set #2 | 6 | 1 |
