| Date | 13 August 2016 — 18:31 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Jaume Campistol |  ESP |
| Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| Bethanie Mattek-Sands / Jack Sock |  USA | 2 | 2 | 6 | 7 | |
| Lucie Hradecká / Radek Štěpánek |  CZE | 0 | 0 | 4 | 6 |
Bethanie Mattek-Sands / Jack Sock| Pos | Competitor | Tie-break 2 | |||
|---|---|---|---|---|---|
| Bethanie Mattek-Sands | – | ||||
| Jack Sock | – | ||||
| Team Totals | 7 | ||||
Lucie Hradecká / Radek Štěpánek| Pos | Competitor | Tie-break 2 | |||
|---|---|---|---|---|---|
| Lucie Hradecká | – | ||||
| Radek Štěpánek | – | ||||
| Team Totals | 3 | ||||
