| Date | 13 August 2016 — 18:31 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Jaume Campistol | ESP |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| – | Bethanie Mattek-Sands / Jack Sock | USA | 2 | 6 | 7 | |
| – | Lucie Hradecká / Radek Štěpánek | CZE | 0 | 4 | 6 |
Bethanie Mattek-Sands / Jack Sock| Pos | Seed | Competitor | Tie-break 2 | |||
|---|---|---|---|---|---|---|
| – | Bethanie Mattek-Sands | – | ||||
| – | Jack Sock | – | ||||
| Team Totals | 7 | |||||
Lucie Hradecká / Radek Štěpánek| Pos | Seed | Competitor | Tie-break 2 | |||
|---|---|---|---|---|---|---|
| – | Lucie Hradecká | – | ||||
| – | Radek Štěpánek | – | ||||
| Team Totals | 3 | |||||