| Date | 11 August 2016 — 17:47 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 8) | |
| Chair Umpire | Mariana Alves |  POR |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| – | Roberta Vinci / Fabio Fognini |  ITA | 2 | 6 | 3 | |
| 2 | Kristina Mladenovic / Pierre-Hugues Herbert |  FRA | 1 | 4 | 6 |
Roberta Vinci / Fabio Fognini| Pos | Seed | Competitor | Match Tie-break | |||
|---|---|---|---|---|---|---|
| – | Roberta Vinci | – | ||||
| – | Fabio Fognini | – | ||||
| Team Totals | 10 | |||||
Kristina Mladenovic / Pierre-Hugues Herbert| Pos | Seed | Competitor | Match Tie-break | |||
|---|---|---|---|---|---|---|
| – | Kristina Mladenovic | – | ||||
| – | Pierre-Hugues Herbert | – | ||||
| Team Totals | 8 | |||||
