1968 Summer Olympics |
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| Trap, Open | Domingo Lorenzo | 55 | |
| Skeet, Open | Riyadh Yunes | 48 | |
| Luis Santana | 52 | ||
1972 Summer Olympics |
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| Skeet, Open | Riyadh Yunes | 58 | |
| Domingo Lorenzo | 62 | ||
2004 Summer Olympics |
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| Skeet, Men | Julio Dujarric | =21 | |
2008 Summer Olympics |
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| Skeet, Men | Julio Dujarric | 31 | |
2012 Summer Olympics |
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| Trap, Men | Sergio Piñero | 20 | |
| Double Trap, Men | Sergio Piñero | DNS | |
2016 Summer Olympics |
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| Trap, Men | Eduardo Lorenzo | 20 |