| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1992 Summer Olympics | Li Fang / Tang Min | =9 | |
| 1996 Summer Olympics | Chen Li / Yi Jingqian | =9 | |
| 2000 Summer Olympics | Li Na / Li Ting | =17 | |
| 2004 Summer Olympics | Li Ting / Sun Tiantian | 1 | Gold |
| Yan Zi / Zheng Jie | =5 | ||
| 2008 Summer Olympics | Yan Zi / Zheng Jie | 3 | Bronze |
| Peng Shuai / Sun Tiantian | =17 | ||
| 2012 Summer Olympics | Peng Shuai / Zheng Jie | =5 | |
| Li Na / Zhang Shuai | =9 | ||
| 2016 Summer Olympics | Peng Shuai / Zhang Shuai | =9 | |
| Xu Yifan / Zheng Saisai | =9 | ||
| 2020 Summer Olympics | Xu Yifan / Yang Zhaoxuan | =9 | |
| Duan Yingying / Zheng Saisai | =17 | ||
| 2024 Summer Olympics | Wang Xinyu / Zheng Saisai | =17 | |
| Yuan Yue / Zhang Shuai | =17 |