| Date | 6 August 2016 — 18:52 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Mariana Alves |  POR |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|
| – | Kirsten Flipkens |  BEL | 2 | 4 | 6 | 7 (7) | |
| 5 | Venus Williams |  USA | 1 | 6 | 3 | 6 (5) |
| Kirsten Flipkens | Venus Williams | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 4 | 6 |
| Set 2 | 6 | 3 |
| Set 3 | 7 (7) | 6 (5) |
