| Date | 7 August 2016 — 18:28 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Carlos Ramos |  POR |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| – | Lucie Šafářová / Barbora Strýcová |  CZE | 2 | 6 | 6 | |
| 1 | Serena Williams / Venus Williams |  USA | 0 | 3 | 4 |
Lucie Šafářová / Barbora Strýcová| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Lucie Šafářová | ||||
| – | Barbora Strýcová | ||||
| Team Totals | |||||
Serena Williams / Venus Williams| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Serena Williams | ||||
| – | Venus Williams | ||||
| Team Totals | |||||
