| Date | 14 August 2016 — 14:32 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | James Keothavong |  GBR |
| Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| Bethanie Mattek-Sands / Jack Sock |  USA | 2 | 2 | 6 | 6 | |
| Venus Williams / Rajeev Ram | USA | 1 | 1 | 7 | 1 |
Bethanie Mattek-Sands / Jack Sock| Pos | Competitor | Match tie-break | Tie-break 1 | |||
|---|---|---|---|---|---|---|
| Bethanie Mattek-Sands | – | – | ||||
| Jack Sock | – | – | ||||
| Team Totals | 10 | 3 | ||||
Venus Williams / Rajeev Ram| Pos | Competitor | Match tie-break | Tie-break 1 | |||
|---|---|---|---|---|---|---|
| Venus Williams | – | – | ||||
| Rajeev Ram | – | – | ||||
| Team Totals | 7 | 7 | ||||
