| Date | 14 August 2016 — 14:32 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | James Keothavong |  GBR |
| Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|
| Bethanie Mattek-Sands / Jack Sock |  USA | 2 | 6 (3) | 6 | |
| Venus Williams / Rajeev Ram | USA | 1 | 7 (7) | 1 |
Bethanie Mattek-Sands / Jack Sock| Pos | Competitor | Match Tie-break | |||
|---|---|---|---|---|---|
| Bethanie Mattek-Sands | – | ||||
| Jack Sock | – | ||||
| Team Totals | 10 | ||||
Venus Williams / Rajeev Ram| Pos | Competitor | Match Tie-break | |||
|---|---|---|---|---|---|
| Venus Williams | – | ||||
| Rajeev Ram | – | ||||
| Team Totals | 7 | ||||
