| Date | 13 August 2016 — 16:52 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Thomas Sweeney |  AUS |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| – | Venus Williams / Rajeev Ram |  USA | 2 | 2 | 6 | |
| 4 | Sania Mirza / Rohan Bopanna |  IND | 1 | 6 | 2 |
Venus Williams / Rajeev Ram| Pos | Seed | Competitor | Match Tie-break | |||
|---|---|---|---|---|---|---|
| – | Venus Williams | – | ||||
| – | Rajeev Ram | – | ||||
| Team Totals | 10 | |||||
Sania Mirza / Rohan Bopanna| Pos | Seed | Competitor | Match Tie-break | |||
|---|---|---|---|---|---|---|
| – | Sania Mirza | – | ||||
| – | Rohan Bopanna | – | ||||
| Team Totals | 3 | |||||
