| Date | 12 August 2016 — 20:04 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Pascal Maria |  FRA |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| – | Venus Williams / Rajeev Ram |  USA | 2 | 6 | 7 | |
| – | Roberta Vinci / Fabio Fognini |  ITA | 0 | 3 | 5 |
Venus Williams / Rajeev Ram| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Venus Williams | ||||
| – | Rajeev Ram | ||||
| Team Totals | |||||
Roberta Vinci / Fabio Fognini| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Roberta Vinci | ||||
| – | Fabio Fognini | ||||
| Team Totals | |||||
