| Archery | 
| Individual, Men | Elías Malavé | =33 |  | 
| Individual, Women | Leidys Brito | =33 |  | 
| Artistic Gymnastics | 
| Individual All-Around, Women | Jessica López | 18 |  | 
| Floor Exercise, Women | Jessica López | 27 r1/2 |  | 
| Uneven Bars, Women | Jessica López | 20 r1/2 |  | 
| Balance Beam, Women | Jessica López | 27 r1/2 |  | 
| Athletics | 
| 400 metres, Men | Alberth Bravo | 6 h2 r2/3 |  | 
| 1,500 metres, Men | Eduard Villanueva | 11 h3 r1/3 |  | 
| Marathon, Men | Pedro Mora | 62 |  | 
| 3,000 metres Steeplechase, Men | José Gregorio Peña | 8 h1 r1/2 |  | 
| 4 × 400 metres Relay, Men | Venezuela | 6 |  | 
|  | Arturo Ramírez • Alberto Aguilar • Alberth Bravo • Omar Longart • José Meléndez | 
| 200 metres, Women | Nercely Soto | 8 h4 r1/3 |  | 
| Marathon, Women | Yolymar Pineda | 90 |  | 
| 20 kilometres Race Walk, Women | Milángela Rosales | 50 |  | 
| Hammer Throw, Women | Rosa Rodríguez | 22 |  | 
| Javelin Throw, Women | Yusbelys Parra | DNS |  | 
| Beach Volleyball | 
| Beach Volleyball, Men | Venezuela | =19 |  | 
|  | Igor Hernández • Jesús Villafañe | 
| Boxing | 
| Welterweight, Men | Gabriel Maestre | =5 |  | 
| Middleweight, Men | José Espinoza | =16 |  | 
| Flyweight, Women | Karlha Magliocco | =5 |  | 
| Cycling BMX Racing | 
| BMX, Women | Stefany Hernández | 9 |  | 
| Cycling Road | 
| Road Race, Individual, Men | Miguel Ubeto | 45 |  | 
|  | Jackson Rodríguez | 50 |  | 
|  | Tomás Gil | 69 |  | 
| Individual Time Trial, Men | Tomás Gil | 33 |  | 
| Road Race, Individual, Women | Danielys García | DNF |  | 
| Cycling Track | 
| Sprint, Men | Hersony Canelón | 12 |  | 
| Keirin, Men | Hersony Canelón | 12 |  | 
| Team Sprint, Men | Venezuela | 9 |  | 
|  | Hersony Canelón • César Marcano • Ángel Pulgar | 
| Omnium, Men | Carlos Linares | 17 |  | 
| Sprint, Women | Daniela Larreal | 16 |  | 
| Keirin, Women | Daniela Larreal | =8 |  | 
| Team Sprint, Women | Venezuela | 7 |  | 
|  | Daniela Larreal • Mariaesthela Vilera | 
| Omnium, Women | Angie González | 18 |  | 
| Diving | 
| Springboard, Men | Robert Páez | 25 |  | 
|  | Edickson Contreras | 28 |  | 
| Springboard, Women | Jocelyn Castillo | 23 |  | 
| Fencing | 
| Épée, Individual, Men | Rubén Limardo | 1 | Gold | 
|  | Silvio Fernández Briceño | =5 |  | 
| Sabre, Individual, Men | Hernán Jansen | =17 |  | 
| Foil, Individual, Women | Johana Fuenmayor | =17 |  | 
| Épée, Individual, Women | María Martínez | =33 |  | 
| Sabre, Individual, Women | Alejandra Benítez | =9 |  | 
| Judo | 
| Extra-Lightweight, Men | Javier Guédez | =9 |  | 
| Half-Lightweight, Men | Ricardo Valderrama | =17 |  | 
| Heavyweight, Women | Giovanna José Blanco | =9 |  | 
| Marathon Swimming | 
| 10 kilometres Open Water, Men | Erwin Maldonado | 13 |  | 
| 10 kilometres Open Water, Women | Yanel Pinto | 13 |  | 
| Sailing | 
| Windsurfer, Men | Daniel Flores | 31 |  | 
| One Person Dinghy, Men | José Ruiz | 41 |  | 
| Shooting | 
| Air Pistol, 10 metres, Women | Maribel Piñeda | 45 |  | 
| Sporting Pistol, 25 metres, Women | Maribel Piñeda | 38 |  | 
| Swimming | 
| 200 metres Freestyle, Men | Cristian Quintero | 22 |  | 
| 400 metres Freestyle, Men | Cristian Quintero | 16 |  | 
| 1,500 metres Freestyle, Men | Alejandro Gómez | 23 |  | 
| 4 × 100 metres Freestyle Relay, Men | Venezuela | 15 |  | 
|  | Cristian Quintero • Octavio Alesi • Marcos Lavado • Crox Acuña | 
| 100 metres Butterfly, Men | Albert Subirats | 29 |  | 
| 200 metres Butterfly, Men | Marcos Lavado | 27 |  | 
| 50 metres Freestyle, Women | Arlene Semeco | 28 |  | 
| 100 metres Freestyle, Women | Arlene Semeco | 33 |  | 
| 400 metres Freestyle, Women | Andreína Pinto | 15 |  | 
| 800 metres Freestyle, Women | Andreína Pinto | 8 |  | 
| 200 metres Butterfly, Women | Andreína Pinto | 22 |  | 
| 400 metres Individual Medley, Women | Andreína Pinto | 27 |  | 
| Table Tennis | 
| Singles, Women | Fabiola Ramos | =49 |  | 
| Weightlifting | 
| Lightweight, Men | Junior Sánchez | 4 |  | 
| Flyweight, Women | Betsi Rivas | 8 |  | 
| Featherweight, Women | Inmara Henrríquez | 8 |  | 
| Wrestling | 
| Lightweight, Greco-Roman, Men | Luis Liendo | 12 |  | 
| Welterweight, Greco-Roman, Men | Wuileixis Rivas | =16 |  | 
| Heavyweight, Greco-Roman, Men | Erwin Caraballo | 19 |  | 
| Middleweight, Freestyle, Men | Ricardo Roberty | 11 |  | 
| Light-Heavyweight, Freestyle, Men | José Díaz | 17 |  | 
| Flyweight, Freestyle, Women | Mayelis Caripá | 16 |  | 
| Lightweight, Freestyle, Women | Marcia Andrades | 19 |  |