China had won the women’s table tennis singles event at the Olympics every year since its inception in 1988, most recently with Zhang Yining, who had earned gold in the singles and the doubles/team categories for the past two editions. Following her retirement, compatriot Ding Ning entered the tournament as the number one seed and the reigning World Champion in the singles and team events. Close behind at number two was Li Xiaoxia, also of China, who had numerous World Championship titles in team and doubles competitions. No other player came close to their dominance, and thus the Chinese were expected to take the top two podium spots and, as Li had a losing record against Ding, Ding came to London as the favorite to win the gold. With China having captured all three medals in the men’s and women’s event at the last Olympics, the International Table Tennis Federation instituted a two entrant per country rule at the tournament, leaving Kim Gyeong-A of South Korea as the number three seed. This would be Kim’s third Olympics: she won bronze in the singles event in 2004 and again in the team event in 2008. The restriction on national entries was not unprecedented, as it had been undertaken in swimming during the 1970s, due to American and East German dominance.
Throughout the tournament Ding seemed to be the stronger player, surrendering only one set out of thirteen through the quarterfinals. Li stumbled at times, but still easily survived to the semi-finals, where she defeated fourth-ranked Kasumi Ishikawa of Japan in five sets. Ding had slightly more trouble overcoming her opponent, Feng Tian Wei of Singapore, but eventually emerged victorious and paved the way for an all-China final. Li displayed an iron determination to defeat her teammate, winning the first two sets 11-8 and 14-12. She then seemed to wear down in the third set, losing 8-11, but picked up again in the fourth with an 11-6 victory. By the fifth set, Li’s momentum was unstoppable and she launched an aggressive barrage against which Ding had no answer. Li won this final set by the widest margin yet, 11-4, and stole the Olympic crown from the favorite. Meanwhile the Chinese-born Feng defeated her Japanese opponent to win the bronze medal, leading China to sweep the podium, at least in spirit, once more.
| Match | Date/Time | Location | Competitor | NOC | Result | Competitor | NOC | |
|---|
| Match #1 | 28 Jul 11:15 | North Arena 1 - Table 3 | Tetiana Bilenko | UKR | 11-4, 11-2, 11-8, 8-11, 11-7 | Paula Medina | COL | |
| Match #2 | 28 Jul 11:15 | North Arena 1 - Table 1 | Cornelia Vajda-Molnar | CRO | 11-6, 11-8, 11-7, 11-5 | Lily Zhang | USA | |
| Match #3 | 28 Jul 11:15 | North Arena 1 - Table 4 | Mie Skov | DEN | 11-9, 11-6, 11-7, 11-9 | Nadeen El-Dawlatly | EGY | |
| Match #4 | 28 Jul 14:30 | North Arena 1 - Table 3 | Wenling Tan Monfardini | ITA | 11-7, 11-5, 12-10, 11-1 | Funke Oshonaike | NGR | |
| Match #5 | 28 Jul 11:15 | North Arena 1 - Table 2 | Krisztina Tóth | HUN | 11-9, 9-11, 9-11, 12-14, 11-5, 11-9, 12-10 | Fabiola Ramos | VEN | |
| Match #6 | 28 Jul 12:00 | North Arena 1 - Table 2 | Nanthana Komwong | THA | 4-11, 3-11, 11-6, 12-14, 11-8, 11-2, 12-10 | Lei Mendes | POR | |
| Match #7 | 28 Jul 14:30 | North Arena 1 - Table 2 | Jian-Fang Lay | AUS | 8-11, 11-1, 11-5, 11-6, 11-1 | Lígia da Silva | BRA | |
| Match #8 | 28 Jul 12:00 | North Arena 1 - Table 1 | Aliaksandra Privalova | BLR | 11-2, 7-11, 11-6, 11-8, 8-11, 11-9 | Xing Han | CGO | |
| Match #9 | 28 Jul 14:30 | North Arena 1 - Table 4 | Mo Zhang | CAN | 8-11, 9-11, 12-10, 9-11, 11-4, 13-11, 16-14 | Melek Hu | TUR | |
| Match #10 | 28 Jul 12:00 | North Arena 1 - Table 4 | Miao Miao | AUS | 11-8, 11-9, 6-11, 7-11, 11-7, 11-7 | Dana Hadačová | CZE | |
| Match #11 | 28 Jul 14:30 | North Arena 1 - Table 1 | Joanna Parker | GBR | 11-7, 11-5, 11-9, 11-5 | Carol Kumahara | BRA | |
| Match #12 | 28 Jul 15:15 | North Arena 1 - Table 4 | Yi Fang Xian | FRA | 8-11, 11-7, 11-7, 11-3, 11-6 | Sarah Hanffou | CMR | |
| Match #13 | 28 Jul 15:15 | North Arena 1 - Table 2 | Dina Meshref | EGY | 12-10, 8-11, 4-11, 9-11, 14-12, 11-9, 11-9 | Yana Noskova | RUS | |
| Match #14 | 28 Jul 12:00 | North Arena 1 - Table 3 | Sara Ramírez | ESP | 11-9, 11-8, 11-7, 8-11, 11-2 | Ankita Das | IND | |
| Match #15 | 28 Jul 15:15 | North Arena 1 - Table 3 | Yuan Tian | CRO | 11-6, 11-6, 11-7, 11-7 | Berta Rodríguez | CHI | |
| Match #16 | 28 Jul 15:15 | North Arena 1 - Table 1 | Ariel Hsing | USA | 11-9, 11-8, 11-3, 11-5 | Yadira Silva | MEX | |
| Match | Date/Time | Location | Competitor | NOC | Result | Competitor | NOC | |
|---|
| Match #1 | 28 Jul 20:30 | North Arena 1 - Table 1 | Daniela Dodean | ROU | 7-11, 8-11, 11-5, 5-11, 11-7, 11-9, 11-2 | Tetiana Bilenko | UKR | |
| Match #2 | 28 Jul 20:30 | North Arena 1 - Table 2 | Kim Jong | PRK | 11-9, 9-11, 11-6, 11-4, 11-8 | Cornelia Vajda-Molnar | CRO | |
| Match #3 | 28 Jul 21:15 | North Arena 1 - Table 1 | Natalia Partyka | POL | 5-11, 11-3, 12-10, 8-11, 9-11, 11-7, 11-9 | Mie Skov | DEN | |
| Match #4 | 29 Jul 09:00 | North Arena 1 - Table 2 | Anna Tikhomirova | RUS | 6-11, 11-6, 11-8, 12-14, 8-11, 11-6, 12-10 | Wenling Tan Monfardini | ITA | |
| Match #5 | 28 Jul 20:30 | North Arena 1 - Table 4 | Chen Szu-Yu | TPE | 10-12, 7-11, 7-11, 15-13, 11-5, 11-5, 13-11 | Krisztina Tóth | HUN | |
| Match #6 | 28 Jul 20:30 | North Arena 1 - Table 3 | Iveta Vacenovská | CZE | 14-16, 11-6, 11-4, 11-5, 11-3 | Nanthana Komwong | THA | |
| Match #7 | 29 Jul 09:00 | North Arena 1 - Table 3 | Xue Li | FRA | 11-7, 13-11, 7-11, 11-3, 9-11, 9-11, 11-6 | Jian-Fang Lay | AUS | |
| Match #8 | 28 Jul 21:15 | North Arena 1 - Table 3 | Liu Jia | AUT | 5-11, 11-4, 11-8, 12-10, 10-12, 11-4 | Aliaksandra Privalova | BLR | |
| Match #9 | 29 Jul 09:00 | North Arena 1 - Table 4 | Li Qiangbing | AUT | 11-9, 9-11, 11-2, 11-9, 11-9 | Mo Zhang | CAN | |
| Match #10 | 28 Jul 21:15 | North Arena 1 - Table 4 | Huang Yi-Hua | TPE | 11-7, 11-9, 11-7, 11-4 | Miao Miao | AUS | |
| Match #11 | 29 Jul 09:00 | North Arena 1 - Table 1 | Kristin Silbereisen | GER | 11-6, 11-7, 7-11, 11-2, 11-4 | Joanna Parker | GBR | |
| Match #12 | 29 Jul 10:00 | North Arena 1 - Table 2 | Yi Fang Xian | FRA | 11-9, 11-6, 6-11, 11-9, 8-11, 11-6 | Ri Myong-Sun | PRK | |
| Match #13 | 29 Jul 10:00 | North Arena 1 - Table 1 | Eliza Samara | ROU | 7-11, 11-7, 13-11, 11-6, 11-8 | Dina Meshref | EGY | |
| Match #14 | 28 Jul 21:15 | North Arena 1 - Table 2 | Marharyta Pesotska | UKR | 11-7, 11-9, 8-11, 13-11, 11-6 | Sara Ramírez | ESP | |
| Match #15 | 29 Jul 10:00 | North Arena 1 - Table 3 | Georgina Póta | HUN | 11-13, 11-4, 11-2, 12-10, 11-2 | Yuan Tian | CRO | |
| Match #16 | 29 Jul 10:00 | North Arena 1 - Table 4 | Ariel Hsing | USA | 11-9, 10-12, 11-9, 11-5, 10-12, 12-10 | Xia Lian Ni | LUX | |
| Match | Date/Time | Location | Competitor | NOC | Result | Competitor | NOC | |
|---|
| Match #1 | 29 Jul 18:00 | North Arena 1 - Table 3 | Ding Ning | CHN | 11-4, 11-3, 11-9, 11-6 | Daniela Dodean | ROU | |
| Match #2 | 29 Jul 18:00 | North Arena 1 - Table 2 | Jiang Huajun | HKG | 11-5, 11-9, 7-11, 11-7, 5-11, 11-7 | Kim Jong | PRK | |
| Match #3 | 29 Jul 18:00 | North Arena 1 - Table 4 | Jie Li | NED | 11-13, 6-11, 16-14, 11-7, 12-10, 11-7 | Natalia Partyka | POL | |
| Match #4 | 29 Jul 18:00 | North Arena 1 - Table 1 | Ai Fukuhara | JPN | 11-7, 11-8, 11-9, 11-3 | Anna Tikhomirova | RUS | |
| Match #5 | 29 Jul 19:00 | North Arena 1 - Table 2 | Feng Tianwei | SGP | 11-6, 11-13, 11-5, 12-10, 11-9 | Chen Szu-Yu | TPE | |
| Match #6 | 29 Jul 19:00 | North Arena 1 - Table 3 | Jiaduo Wu | GER | 11-9, 15-13, 8-11, 11-8, 9-11, 11-5 | Iveta Vacenovská | CZE | |
| Match #7 | 29 Jul 19:00 | North Arena 1 - Table 4 | Yanfei Shen | ESP | 11-5, 11-2, 11-8, 11-3 | Xue Li | FRA | |
| Match #8 | 29 Jul 19:00 | North Arena 1 - Table 1 | Kim Gyeong-A | KOR | 11-8, 6-11, 11-4, 11-5, 11-9 | Liu Jia | AUT | |
| Match #9 | 29 Jul 20:00 | North Arena 1 - Table 2 | Kasumi Ishikawa | JPN | 11-13, 10-12, 11-7, 12-10, 11-8, 11-5 | Li Qiangbing | AUT | |
| Match #10 | 29 Jul 20:00 | North Arena 1 - Table 3 | Qian Li | POL | 11-7, 11-8, 11-6, 11-3 | Huang Yi-Hua | TPE | |
| Match #11 | 29 Jul 20:00 | North Arena 1 - Table 1 | Viktoryia Paulovich | BLR | 12-10, 13-11, 9-11, 11-13, 11-4, 11-7 | Kristin Silbereisen | GER | |
| Match #12 | 29 Jul 20:00 | North Arena 1 - Table 4 | Wang Yuegu | SGP | 11-9, 11-8, 11-6, 11-4 | Yi Fang Xian | FRA | |
| Match #13 | 29 Jul 21:00 | North Arena 1 - Table 4 | Eliza Samara | ROU | 11-9, 11-9, 11-8, 6-11, 5-11, 11-8 | Tie Ya Na | HKG | |
| Match #14 | 29 Jul 21:00 | North Arena 1 - Table 1 | Jiao Li | NED | 11-3, 11-9, 11-4, 11-4 | Marharyta Pesotska | UKR | |
| Match #15 | 29 Jul 21:00 | North Arena 1 - Table 3 | Park Mi-Yeong | KOR | 3-11, 11-8, 11-8, 11-6, 11-9 | Georgina Póta | HUN | |
| Match #16 | 29 Jul 21:00 | North Arena 1 - Table 2 | Li Xiaoxia | CHN | 11-4, 9-11, 11-6, 6-11, 11-8, 11-9 | Ariel Hsing | USA | |
| Match | Date/Time | Location | Competitor | NOC | Result | Competitor | NOC | |
|---|
| Match #1 | 30 Jul 15:30 | North Arena 1 - Table 4 | Ding Ning | CHN | 12-10, 11-2, 11-5, 9-11, 11-6 | Jiang Huajun | HKG | |
| Match #2 | 30 Jul 15:30 | North Arena 1 - Table 2 | Ai Fukuhara | JPN | 11-4, 8-11, 8-11, 6-11, 11-5, 11-8, 11-8 | Jie Li | NED | |
| Match #3 | 30 Jul 15:30 | North Arena 1 - Table 1 | Feng Tianwei | SGP | 11-6, 7-11, 11-5, 9-11, 11-6, 11-6 | Jiaduo Wu | GER | |
| Match #4 | 30 Jul 15:30 | North Arena 1 - Table 3 | Kim Gyeong-A | KOR | 11-8, 11-9, 11-6, 9-11, 11-7 | Yanfei Shen | ESP | |
| Match #5 | 30 Jul 16:30 | North Arena 1 - Table 4 | Kasumi Ishikawa | JPN | 11-9, 11-5, 10-12, 14-12, 11-6 | Qian Li | POL | |
| Match #6 | 30 Jul 16:30 | North Arena 1 - Table 2 | Wang Yuegu | SGP | 11-8, 7-11, 4-11, 12-14, 11-7, 11-9, 11-8 | Viktoryia Paulovich | BLR | |
| Match #7 | 30 Jul 16:30 | North Arena 1 - Table 3 | Jiao Li | NED | 11-5, 8-11, 13-11, 6-11, 11-9, 11-7 | Eliza Samara | ROU | |
| Match #8 | 30 Jul 16:30 | North Arena 1 - Table 1 | Li Xiaoxia | CHN | 6-11, 11-7, 11-6, 11-5, 11-6 | Park Mi-Yeong | KOR | |